页岩油生产过程中的动力学研究,已有半个多世纪的历史了。近几年来,随着干酪根成油学说的发展,为了揭示成烃机理,关于油页岩和生油岩干酪根热降解反应动力学的研究,引起了许多石油地球化学工作者的极大兴趣。 国外对某些油页岩热解动力学参数的测定结果是,热解过程近似一级反应,表观活化能约为13—52.5 kcal/mol;国内华东石油学院王庭芬等用差热分析测定了两个含 The kinetics of shale oil production has been more than half a century old. In recent years, with the development of kerogen theory, in order to reveal the mechanism of hydrocarbon generation, the research on thermal degradation kinetics of kerogen in oil shale and source rock has aroused great interest of many petroleum geochemical workers . Abroad, some of the oil shale pyrolysis kinetic parameters of the determination results, the pyrolysis process is approximately a reaction, the apparent activation energy of about 13-52.5 kcal / mol; East China Petroleum Institute Wang Tingfen and other differential thermal analysis measured Two containing