【摘 要】
：
A series of azomethine esters,3-hydroxy-4-{[(4-iodophenyl)imino]methyl}phenyl alkanoates possessing even number of carbon atoms at the terminal alkanoyloxy chai
【机 构】
：
Department of Chemical Science,Faculty of Science,Universiti Tunku Abdul Rahman,Jln Universiti,Banda
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
A series of azomethine esters,3-hydroxy-4-{[(4-iodophenyl)imino]methyl}phenyl alkanoates possessing even number of carbon atoms at the terminal alkanoyloxy chain(C_(n-1)H_(2n-1)COO-,n = 4,6,8,10,12,14) was synthesized.n-Butanoyloxy was found non-mesogenic,whilst n-hexanoyloxy to n-tetradecanoyloxy exhibited enantiotropic smectic A phase with fan-shaped texture.It was found that the length of terminal alkanoyloxy chain influenced the mesomorphic properties.
A series of azomethine esters, 3-hydroxy-4 - {[(4-iodophenyl) imino] methyl} phenyl alkanoates possessing even number of carbon atoms at the terminal alkanoyloxy chain (C n -1) H 2n -1 COO -, n = 4,6,8,10,12,14) was synthesized.n-Butanoyloxy was found non-mesogenic, whilst n-hexanoyloxy to n-tetradecanoyloxy in enantiotropic smectic A phase with fan-shaped texture. It was found that the length of terminal alkanoyloxy chain influenced the mesomorphic properties.
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