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本文报道了一些新的长碳链季铵化合物的制备,应用这些化合物制得了I~-,NO_3~-,ClO_4~-,IO_4~-,SCN~-,N_3~-,WO_4~-等无机阴离子选择电极;BF_4~-、TaF_6~-、NbF_7~-、CrO_3F~-等络合阴离子电极以及苦味酸根、烷(芳)基磺酸根(阴离子洗涤剂)电极、磺原酸根、水杨酸根、糖精、安乃近等药物及其它有机分子的电极。还讨论了它们在阴离子选择电极中的结构效应。其中有些电极已经作为商品生产,并广泛应用于各种分析领域。
In this paper, some new long carbon chain quaternary ammonium compounds were prepared. These compounds were used to prepare inorganic anions such as I ~, NO_3 ~, ClO_4 ~ -, IO_4 ~ -, SCN ~ -, N_3 ~ - and WO_4 ~ The selective electrode; complex anion electrode such as BF_4 ~ -, TaF_6 ~ -, NbF_7 ~ -, CrO_3F ~ - and picrate, alkane sulfonate (anion detergent) electrode, sulfonate, salicylate, , Analgin and other drugs and other organic molecules. Their structural effects in anion selective electrodes are also discussed. Some of these electrodes have been produced as commercial products and are widely used in various analytical fields.