论文部分内容阅读
The title complex [Cp*Ru(η6-C6H5BPh3)] has been synthesized by the reaction of [Cp*Ru(H2O)(NBD)]BF4 with H2 and NaBPh4, and its crystal structure was determined by single- crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P with a = 11.0610(10), b = 11.2317(10), c = 12.3633(11) , α = 81.419(2), β = 67.8370(10), γ = 88.370(2)o, V = 1405.9(2) 3, Z = 2, C34H35BRu, Mr = 555.50, Dc = 1.312 g/cm3, F(000) = 576 and μ(MoKa) = 0.577 mm-1. The final R and wR are 0.0559 and 0.1483, respectively for 4365 observed reflections with I > 2((I). In the title complex, the four phenyl rings bonded to the B atom are deposited in a tetrahedral geometry, and one of the phenyl rings is η6-bonded to ruthenium.
The title complex [Cp * Ru (η6-C6H5BPh3)] has been synthesized by the reaction of [Cp * Ru (H2O) (NBD)] BF4 with H2 and NaBPh4, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P with a = 11.0610 (10), b = 11.2317 (10), c = 12.3633 11, α = 81.419 (2), β = 67.8370 88.370 (2) o, V = 1405.9 (2) 3, Z = 2, C34H35BRu, Mr = 555.50, Dc = 1.312 g / cm3, F (000) = 576 and μ (MoKa) = 0.577 mm-1. final R and wR are 0.0559 and 0.1483, respectively for 4365 observed reflections with I> 2 ((I). In the title complex, the four phenyl rings bonded to the B atom are deposited in a tetrahedral geometry, and one of the phenyl rings is η6-bonded to ruthenium.