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Samples of fog water collected in the area of Guangzhou during February,March and April of 2005 are used in this work to study the chemical composition of fog water in polluting fog there. Three typical episodes of polluting tbg are analyzed in terms of ionic concentration and their possible sources. It is fuund that the concentration of various ions in fog water is much higher than those in rainwater. Fog not only blocks visual range but contains liquid particles that result in high degree of pollution and are very harmful to human health. SO4= is the anion with the highest concentration in fog water,followed by NO3.For the cation,Ca++ and NH4+ are the highest in concentration. It is then known that rainwater is more acidic than lbg water,indicating that ionic concentration of lbg water is much higher than that of rainwater,but there are much more buffering materials in fog water,like NH4+ and Ca++. There is significant enrichment of Ca++,SO4=. and Mg++ in fog water. In the Guangzhou area,tbg water from polluting fog is mainly influenced continental environment and human activity. The episodes of serious fog pollution during the time have immediate relationships with the presence of abundant water vapor and large amount of polluting aerosol particles.