论文部分内容阅读
本文首次报道了羟基乙酸、邻菲罗啉与铕(Ⅲ)的三元固态配合物通过红外、紫外、荧光、热分析、元素与化学分析确定了配合物的化学组成和分子结构;讨论了配合物的摩尔电导和溶解性;采用量子化学INDO/F方法计算了三元固态配合物的电子结构,依据计算结果讨论了三元固态配合物的成键特征。
In this paper, the chemical composition and molecular structure of glycolic acid, o-phenanthroline and ternary europium (Ⅲ) ternary complexes were reported for the first time by means of IR, UV, fluorescence, thermal analysis, elemental and chemical analysis. The molar conductance and the solubility of the ternary complexes were calculated. The electronic structures of the ternary complexes were calculated by using the quantum chemical INDO / F method. The bonding characteristics of the ternary complexes were discussed.