Preparation and characteristic of NASICON ceramics

来源 :稀有金属(英文版) | 被引量 : 0次 | 上传用户:mai120117
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Hot-pressed sintering was employed to prepare the sodium super ionic conductor (Na1+xZr2SixP3-xO12,1.8≤x≤2.2)ceramics and compare with the sample obtained from normal-press sintering. The phase formation, density, and conductivity of the hot-press sintered and the normal-press sintered samples were investigated in detail. Results show that the density of NASICON ceramics and the degree of crystallization can be improved by hot-press process efficiently. The density of the sample sintered by normal sintering is obviously lower than that sintered by hot press. XRD analysis indicates all the hot press sintered samples contain mainly monoclinic NASICON and no ZrO2 phase was found. The ionic conductivity of normal-press sintered sample is much lower than that of hot-press sintered sample. When the composition is close to Na3Zr2Si2PO12 , the dc conductivities of the hot press sintered samples were in the order of 10-3 S·cm-1.The variation of the ac conductivity with frequency in the high frequency region agrees with the power law feature of σ(ω) ∝ωn(0<n<1).
其他文献
Multiplicative multifractal process could well model video traffic. The multiplier distributions in the multiplicative multifractal model for video traffic are
A 3-dimensional (3D) micromagnetic model combined with Fast Fourier Transform (FFT) method was built up to study the writability in the L10 FePt perpendicular m
Nitrogen-doped, p-type ZnO thin films were grown successfully on sapphire (0001) substrates by using atomic layer epitaxy (ALE). Zn(C2H5)2 [Diethylzinc, DEZn],
Polyvinyl alcohol(PVA) physiological saline gel was prepared using physiological saline solution of the polymer by freezing and thawing method. The influences o
The electronic singlet vertical excited states of photosynthetic reaction center (PSRC) in Rhodopseudomonas (Rps.) viridis were investigated by ZINDO and INDO/S
Pyrolytic resin carbon anode for lithoum ion batteries was prepared from thermosetting phenolic resin.Pyrolysis of the primary phenolic resin and the dewatered
The segregation and diffusion of boron during heat treatments were studied.The influence of boron contents, aging time and applied stress on FeMo2B2 formation w
Elementary waves in Suliciu model for dynamic phase transitions are obtained through traveling wave analysis. For any given initial data with two pieces of cons
Gyroscopic dynamic system can be introduced to Hamiltonian system. Based on an adjoint symplectic subspace iteration method of Hamiltonian gyroscopic system,an
Vanadium oxide nanotubes were synthesized by hydrothermal treatment from V2O5·nH2O sols as precursor and dodecylamine as structure-directing template. The morp