论文部分内容阅读
在343~363K、硫酸与氯化钾摩尔比为1.2∶1、硫酸浓度在55%~75%的条件下,通过实验研究了硫酸分解氯化钾的反应动力学,结果表明:转化反应受化学反应控制、其表观活化能为72.75kJ/mol,相应反应速率的数学模型为:-ln(1-x)=3.909×10-4×exp(-72.75/RT)·t
The reaction kinetics of potassium chloride decomposition by sulfuric acid was studied experimentally at 343-363 K with sulfuric acid to potassium chloride molar ratio of 1.2: 1 and sulfuric acid concentration of 55% -75%. The results showed that the conversion reaction Under the control of chemical reaction, the apparent activation energy was 72.75 kJ / mol and the corresponding reaction rate was: -ln (1-x) = 3.909 × 10-4 × exp (-72.75 / RT) · T