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用动态光散射技术跟踪了海藻酸钠水溶液在0.1mol/LCaCl2水溶液中透析凝胶化的过程。表现出随反应进行,平均衰减速率(线宽)Γ明显减慢及以lgβ1/2g(1)(τ)对τ作图表明体系运动模式复杂的特点,这里g(1)(τ)和τ分别是归一化电场时间相关函数及延迟时间。最后还以平均特征松弛时间τc(≡Γ-1)对透析时间t作图,定量描述了该凝胶化反应的动力学过程。
The dynamic light scattering technique was used to trace the dialysis gelation of sodium alginate solution in 0.1 mol / L aqueous solution of LCaCl2. Showed that the average decay rate (line width) Γ significantly slowed down and the complex kinematic model was characterized by 1gβ1 / 2g (1) (τ) versus τ where g (1) (τ) and τ Respectively, normalized electric field time correlation function and delay time. Finally, the average characteristic relaxation time τc (≡Γ-1) on the dialysis time t mapping, quantitative description of the gelation reaction kinetics.