Highly sensitive and selective chemosensor for Cu~(2+) detection based on a N-propargyl rhodamine 6G

来源 :Science China(Chemistry) | 被引量 : 0次 | 上传用户:Pkulibo
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A novel fluorescence “turn-on” probe for Cu2+ detection has been designed based on a Cu2+ triggered spirolactam ring-opening reaction.The synthetic probe is a double-responsive fluorescent and colorimetric Cu2+-specific sensor.In aqueous solution,it exhibits high selectivity and excellent sensitivity.With a significant color change visible to the naked eye at the concentration of 3 μM(ca.0.19 mg/L),about one magnitude lower than the WHO(World Health Organization) recommended level(2.0 mg/L) for Cu2+ ions in drinking water,the probe could be used to monitor Cu2+ ions in drinking water. A novel fluorescence “turn-on” probe for Cu2 + detection has been designed based on a Cu2 + triggered spirolactam ring-opening reaction. The synthetic probe is a double-responsive fluorescent and colorimetric Cu2 + -specific sensor.In aqueous solution, it exhibits high selectivity and excellent sensitivity. With a significant color change visible to the naked eye at the concentration of 3 μM (ca.0.19 mg / L), about one magnitude lower than the WHO (World Health Organization) recommended level (2.0 mg / L ) for Cu2 + ions in drinking water, the probe could be used to monitor Cu2 + ions in drinking water.
其他文献
为确保《黑龙江省志·水利志》(1986~2005)的编纂质量,实现编纂规范统一,在志稿编写中,应遵照志书体例要求,并严格执行《黑龙江省水利志编纂行文规定》。现针对各承编单位实际
本文论述简体字、繁体字的转换,同时介绍了一个具有某些“准智能”功能的实用的自动转换系统.该系统已实现由简体字到繁体字的高质量和高速度转换,并可在IBM PC/XT,AT及其兼容机上运行. Thi
架标是图书馆用来揭示图书排架方法与范围等特征的标志。开架书库的读者人数众多,类型复杂,搞好架标的设计颇为重要。目前,传统的架标法,大都是以每排书架侧面挡板上方的架
目前,世界各国将有机氯农药在人体脂肪、血液、尿液、耵聍、乳汁中的残留,作为食物环境污染的重要指标之一。为了解重庆市不同人群人乳中有机氯农药残留水平,我站于1980年9~1
基于考虑了氢同位素效应的DTO(1A1)分子的多体展式分析势能函数,用准经典的Monte-Carlo轨迹法研究了O+DT(0,0)体系的分子反应动力学过程.结果表明,在碰撞能较低时(
口服溴隐亭治疗高泌乳素血症有较高的副作用发生率。作者为评价溴隐亭阴道给药法治疗高泌素血症妇女的效果,在连续非选择地对15例泌乳和高泌乳素血症妇女进行治疗。15例中10
目的:采用反相高效液相色谱法测定浓维磷糖浆中咖啡因和维生素B1的含量。  方法:采用 Diamonsil C18 柱(250mm*4.6mm,5um),以甲醇-庚烷磺酸钠缓冲液为流动相(10:90),检测波长为272nm 。  结果:咖啡因与维生素B1浓度分别在3.5~282.6μg/ml(r=1.0000)和0.7~54.7μg/ml (r=0.9999)内与峰面积呈良好的线性关系(n=9),方
研究了B位掺杂的Sr3P2-xVxO8(0≤x≤2.0)基质和Eu3+掺杂Sr3-3yEu2yP1.2V0.8O8(0
人体感染疾病是侵犯的病原菌,宿主及环境三者复杂相互作用的结果。这问题在人体皮癣菌感染上的表现也明显。急性感染常为短期且易治疗。患者有良好的纲胞性免疫,短时期抗皮
淤地坝是在黄土高原丘陵沟壑区各级沟道中兴建的缓洪拦泥淤地工程,用以拦蓄径流泥沙、控制沟蚀,防治水土流失、滞洪、拦泥、淤地(坝地),减少入黄泥沙、充分利用水沙资源。在