通过水热法合成了一个新的配位聚合物[Zn(C2O4)(1,3-bix)]n(1,H2C2O4=草酸,1,3-bix=1,3-双(咪唑基-1-甲基)-苯)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。该配合物属于三斜晶系,P1空间群。在晶体结构中,锌原子为六配位与来自2个不同的C2O42-配体上的4个羧基氧原子和来自2个不同的1,3-bix配体上的2个氮原子配位,呈现畸变的八面体几何构型。而且该配合物通过氢键和π-π堆积作用扩展成三维超分子网状结构。此外还研究了它的荧光性质。 A new coordination polymer [Zn (C2O4) (1,3-bix)] n (1, H2C2O4 = oxalic acid and 1,3-bix = -methyl) -benzene). Elemental analysis, IR, TG and X-ray single crystal diffraction measurements were carried out. The complex belongs to the triclinic system, P1 space group. In the crystal structure, the zinc atom is hexacoordinated to coordinate with four carboxy oxygen atoms from two different C202-ligands and two nitrogen atoms from two different 1,3-bix ligands, Distorted octahedral geometry. Moreover, the complex expands into a three-dimensional supramolecular network by hydrogen bonding and π-π stacking. In addition it also studied its fluorescence properties.