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1.對高頻滴定用的C式和L式滴定池,Q表法,Z表法及F表法测定得到的滴定曲線,與溶液電導改變的關係,用等效電路的理論,作了全面的討論。除C式滴定池Q表法測定,文獻中已有討論外,L式滴定池Q表法測定時,和C式滴定池Z表法和F表法測定時,滴定過程中測定的量都與溶液的電導值單調變化。 2.指出了文獻中的錯誤。C式滴定池應用等效串聯電路與等效並聯電路計算的結果,是完全等同的。C式滴定池的高頻電能損耗與溶液中電解質濃度的關係,與Debye-Falkenhagen效應無關。 3.提出了用鉑絲電極直接插入溶液的高頻滴定法。
1. For the high-frequency titration with C-type and L-type titration cell, Q table, Z table and F table measured titration curve, and the relationship between the change of solution conductance, using the equivalent circuit theory, made a comprehensive discussion. In addition to the C-type titration cell Q table determination, has been discussed in the literature, the L-type titration cell Q table method, and C-type titration cell Z table method and F table method, the determination of the amount of titration process and The conductance of the solution changes monotonically. 2. Point out the mistakes in the literature. C-type titration tank equivalent series circuit and the equivalent parallel circuit results are exactly the same. The relation between the high-frequency power loss of C-type titration cell and the concentration of electrolyte in solution has nothing to do with the Debye-Falkenhagen effect. Proposed a platinum wire electrode directly into the solution of high-frequency titration.