通过联苯甲酰双缩肼（Ｌ）与不同金属乙酸盐［Ｍ（ＯＡｃ）２］及２，３－二氯－５，６－二氰基对苯醌自由基离子（ＤＤＱ－·）反应，合成了３个分子式为（ＭＬ）２＋（ＤＤＱ－·）２（Ｍ＝Ｍｎ、Ｚｎ、Ｃｄ）的三元配合物及２个分子式为（ＭＬ）２＋（ＤＤＱ－·）（ＯＡｃ－）（Ｍ＝Ｎｉ、Ｐｂ）的四元配合物．元素分析确定了它们的组成，经红外光谱、紫外－可见光谱及摩尔电导的测定对其配位情况进行了讨论．另将丁二酮双缩肼（Ｌ）与不同金属乙酸盐［Ｍ（ＯＡｃ）２］，及中性ＤＤＱ反应，合成了分子式分别为（ＭＬ）２＋（ＤＤＱ－·）（ＯＡｃ－）（Ｍ＝Ｃｕ、Ｃｄ）、（ＭＬ）２＋（ＤＤＱ）（ＯＡｃ－）２（Ｍ＝Ｃｏ、Ｎｉ）及（ＨｇＬ）２＋（ＤＤＱ）１．５（ＯＡｃ－）２的五个四元配合物．经元素分析、红外光谱、紫外－可见光谱，对它们进行了表征．固体电导的测定结果表明，含中性ＤＤＱ的配合物均属半导体范畴，其中Ｈｇ配合物的室温粉末固体电导率达３．７×１０－４Ω－１ｃｍ－１． By the reaction of dibenzylidenehydrazide (L) with different metal acetate [M (OAc) 2] and 2,3-dichloro-5,6-dicyano-p-benzoquinone free radical ion , Three ternary complexes of (ML) 2+ (DDQ-) 2 (M = Mn, Zn, Cd) and two complexes of (ML) 2+ (DDQ- ·) (M = Ni, Pb) of the quaternary complex. Elemental analysis confirmed the composition of these compounds. The coordination of these compounds was investigated by FTIR, UV-Vis and molar conductance measurements. In addition, diacetyl bis (hydrazine) diacetate (L) was reacted with different metal acetate [M (OAc) 2] (OAc-) 2 (M = Co, Ni), and (HgL ") 2+ (DDQ) 1.5 Yuan complex. They were characterized by elemental analysis, IR and UV-Vis spectra. The results of solid conductivity measurements show that the complexes containing neutral DDQ belong to the semiconducting domain. The conductivity of Hg complexes at room temperature is 3.7 × 10-4Ω-1cm-1.