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A 3-D inorganic-organic hybrid framework microporous material [Co 3(BDC) 3(EG) 4]·2DMF was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by a direct method and refined by full-matrix least-square method. The crystal is the triclinic system and belongs to space group P-1 with a=9.978(2) nm, b=11.223(2) nm, c=11.283(2) nm, α=102.26(3)°, β=113.52(3)°, γ=92.73(3)°, V=6.329(2) nm 3, Z=1, D c=1.565 Mg/m 3, M r=1 063.59, μ=1.183 mm -1, F(000)=541, GOF=1.024, R=0.044 2, wR=0.124 9.
The crystal structure was solved by using single crystal X-ray diffraction. The crystal structure was solved The crystal is the triclinic system and belongs to space group P-1 with a = 9.978 (2) nm, b = 11.223 (2) nm, c = 11.283 ( (2) nm, α = 102.26 (3) °, β = 113.52 (3) °, γ = 92.73 (3) °, V = 6.329 (2) nm 3, Z = 1, D c = 1.565 Mg / M r = 1 063.59, μ = 1.183 mm -1, F (000) = 541, GOF = 1.024, R = 0.044 2, wR = 0.124 9.