【摘 要】
：
A new compound formulated [Ag2(idc)](NO3)(H2O (H2idc = iminodiacetic acid) was synthesized under mild conditions and characterized by IR spectrum and single-cry
【机 构】
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State Key Laboratory of Structural Chemistry
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A new compound formulated [Ag2(idc)](NO3)(H2O (H2idc = iminodiacetic acid) was synthesized under mild conditions and characterized by IR spectrum and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group of P21/n with a = 5.5029(2), b = 11.1316(5), c = 15.5319 (1) (A), β = 96.038(3)°, V = 946.15(6) (A)3, Z = 4, R = 0.0619 and wR = 0.1606. Its structure is a 2D polymer, whose repeat units consist of dinuclear silver cluster coordinated by two bridging iminodiacetic acids. In the complex, the Ag(I) ions adopt three coordinate fashions, and the Ag-Ag metal-metal contacts of 2.8418 (A) are observed.
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