论文部分内容阅读
以2-氯乙胺盐酸盐和芳香醛为原料在三乙胺和无水硫酸镁存在的条件下进行缩合反应,制得了N-(2-氯乙基)-芳香醛亚胺。将此类亚胺化合物与醇钠的醇溶液进行反应,得到了异常的产物N-(1-烷氧基乙基)-芳香醛亚胺。初步讨论了后一反应的机理。
The condensation reaction of 2-chloroethylamine hydrochloride and aromatic aldehyde in the presence of triethylamine and anhydrous magnesium sulfate gave N- (2-chloroethyl) -aromatic aldimine. Reaction of this imine with an alcoholic sodium alkoxide gives the unusual product N- (1-alkoxyethyl) -aromatic aldimine. Preliminary discussion of the mechanism of the latter reaction.