孔隙水渗流通量对渗漏型天然气水合物影响的数值模拟

来源 :中国科学:地球科学 | 被引量 : 0次 | 上传用户:spsnake
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
海底冷泉活动区不仅有天然气向海底的渗漏,同时还存在孔隙水的对流,并可能改变天然气水合物体系的温度和盐度,进而影响天然气水合物的成藏.利用建立的天然气水合物生成动力学模型和水合物脊南部高地实测的温度和盐度等条件,模拟了三种典型流体活动区(生物蛤区、细菌席区和冒气区)不同的流体通量条件下天然气水合物的成藏过程.其中生物蛤区孔隙水通量<20kgm-2a-1,模拟表明孔隙水对流作用对体系的温度和盐度无影响或影响很小,由于天然气水合物生成作用,体系盐度升高显著(最高>0.8mol kg-1),温度发生一定的升高,天然气水合物稳定带底界逐步升高到约70mbsf,水合物饱和度高.细菌席区孔隙水通量100~2500kg m-2a-1,孔隙水对流作用抑制了盐度升高,同时使体系温度升高显著,模拟的盐度为海水值或略高于海水值(<0.65mol kg-1),同时天然气水合物稳定带底界显著上升到浅层50mbsf以上,甚至可达浅层3mbsf,天然气水合物饱和度较低.而在冒气区,孔隙水通量可达1010kg m-2a-1,经历9min渗漏,通道温度达到流体源区值,通道内无天然气水合物生成.因而,模拟结果表明孔隙水通量越高,孔隙水盐度越低,温度上升越显著,天然气水合物稳定带底界上移越显著,单位面积天然气水合物生成速率也越低,天然气水合物饱和度越小,天然气水合物资源量越小. The seabed cold spring activity zone not only has the natural gas leakage to the seafloor, but also the pore water convection, and may change the temperature and salinity of the gas hydrate system, thus affecting the gas hydrate accumulation. Using the established gas hydrate formation Kinetic model and the temperature and salinity measured in the southern highlands of the hydrate ridges, simulated the effects of different gas fluxes on the gas hydrate of the three typical fluid activity zones (bio-clam zone, bacterial zone and aeration zone) The pore water flux in biological clam zone is less than 20kgm-2a-1. The simulation shows that the convection of pore water has no or little effect on the temperature and salinity of the system. Because of the formation of gas hydrate, (Up to> 0.8mol kg-1), the temperature increased to a certain extent, and the bottom boundary of gas hydrate stability gradually increased to about 70mbsf, the hydrate saturation was high.The pore water flux of bacteria was 100 ~ 2500kg m -2a-1. The convection of pore water suppressed the salinity increase and the temperature of the system increased significantly. The simulated salinity was slightly higher than seawater (<0.65mol kg-1), and the natural gas hydrate Stable bottom line significantly Up to shallow 50mbsf, even up to shallow 3mbsf, natural gas hydrate saturation is low, while in the rised area, pore water flux up to 1010kgm-2a-1, after 9min leakage, the channel temperature reaches the fluid Source zone value and no formation of gas hydrate in the channel.Therefore, the simulation results show that the higher the pore water flux, the lower the pore water salinity, the more significant the temperature rise, the more the gas hydrate stable bottom zone moves up significantly, and the unit area Natural gas hydrate formation rate is also lower, the smaller the natural gas hydrate saturation, the smaller the amount of natural gas hydrate resources.
其他文献
通过液相法制备出钨酸/DWCNTs和纯钨酸2种前驱体,然后在氮气气氛下焙烧至700℃,保温2 h,分别生成了WO_3/DWCNTs和WO_3粉末。采用扫描电子显微镜和X射线衍射仪对产物的形貌和
数字档案馆研究是当前档案学研究领域的一个热点问题。据笔者在中国期刊网上统计,2000至2004年5年间“篇名”中含有“数字档案馆”字眼的研究论文共计160篇。“数字档案馆研
1 病例报告患者女,65岁。因陈旧性心肌梗塞、心绞痛人院。入院后遵医嘱做溶栓清[军队医院制剂,沈联制字(2000)FW99002号]过敏试验。观察15min,无阳性反应。将溶栓清90mg加人
Y-chromosome microdeletion in male fetuses conceived by intracytoplasmic sperm injection (ICSI) was screened by polymerase chain reaction for sequence-tagged si
我今天报告的主题,是有关家庭阅读活动与公共图书馆读者工作之间的关系。我的基本观点是,家庭阅读活动应当与图书馆导读工作相辅相成,图书馆导读工作应当与全国各地建设“学
本文针对某项目的要求,详细介绍了45°倾斜管固定焊(6G)焊接的试件制备、装配、焊接的过程、操作要点及注意事项,并使参加考试焊工均取得了6G资质,为某项目的启动及最终完成
中药甘草的主要成份为甘草酸,本文提取甘草的主要成分β-甘草酸,通过特殊工艺研制出α-甘草酸,制成中药制剂肝力注射液,临床使用表明肝力注射液为治疗乙肝的良药.
中国涂料工业协会中涂协(2013)协字第026号各涂料、颜料及相关单位:2013年,我国涂料产业在国家“稳中求进”的宏观政策调控下,努力推进产品结构调整与发展方式的转变,在致力
国家质检总局于2006年10月24日就关于尿素合成塔出料管结构设计提出如下意见:为加强尿素合成塔安全监察工作,国家质检总局于2005年8月24日印发了《关于进一步加强尿素合成塔
建立了土壤中硝磺草酮及其代谢物4-甲砜基-2-硝基苯甲酸(MNBA)和2-氨基-4-甲砜基苯甲酸(AMBA)残留的超高效液相色谱-串联质谱(UPLC-MS/MS)分析方法。样品用0.1%氨水-乙腈溶液