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本文介绍一五胺配合物[Co(terpy)(bpy)Cl]~(2+),三元胺是2,2′:6′,2″三联吡啶,二元胺是2,2′-联吡啶,此配合物结构特殊在于分子中没有任何酸性氢。利用其考察非碱催化水解过程中发现,该配合物的水解速率出人意料地快。这个取代反应可能是一氧化还原过程。
This article describes the Pentamine complex [Co (terpy) (bpy) Cl] 2+, the triamine is 2,2 ’: 6’, 2 "terpyridine and the diamine is 2,2’- , The special structure of this complex is that there is not any acidic hydrogen in the molecule.Using it to investigate the non-base catalytic hydrolysis process, the rate of hydrolysis of this complex is surprisingly fast.The substitution reaction may be a redox process.