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The thermal decompositions of two systems(No.1,KClO3(52.2％)/CuO(26.0％)/S(9.6％)/Mg-Al(3.5％)/C6Cl6(4.35％) and No.2,KClO3(52.2％)/CuO(26.0％)/S(9.6％)/Mg-Al(3.5％)/C6Cl6(4.35％) are studied using Accelerating Rate Calorimeter (ARC). Temperature vs time curve and