NOx storage and reduction assisted by non-thermal plasma over Co/Pt/Ba/γ-Al2O3 catalyst using CH4 as

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NOx storage and reduction(NSR)technology has been regarded as one of the most promising strategies for the removal of nitric oxides(NOx)from lean-burn engines,and the potential of the plasma catalysis method for NOx reduction has been confirmed in the past few decades.This work reports the NSR of nitric oxide(NO)by combining non-thermal plasma(NTP)and Co/Pt/Ba/γ-Al2O3(Co/PBA)catalyst using methane as a reductant.The experimental results reveal that the NOx conversion of NSR assisted by NTP is notably enhanced compared to the catalytic efficiency obtained from NSR in the range of 150 ℃-350 ℃,and NOx conversion of the 8%Co/PBA catalyst reaches 96.8%at 350℃.Oxygen(O2)has a significant effect on the removal of NOx,and the NOx conversion increases firstly and then decreases when the O2 concentration ranges from 2%to 10%.Water vapor reduces the NOx storage capacity of Co/PBA catalysts on account of the competition for adsorption sites on the surface of Co/PBA catalysts.There is a negative correlation between sulfur dioxide(SO2)and NOx conversion in the NTP system,and the 8%Co/PBA catalyst exhibits higher NOx conversion compared to other catalysts,which shows that Co has a certain SO2 resistance.
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