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Using oxalic acid and stoichiometrically mixed solution of NiCl2, CoCl2, and MnCl2 as starting materials, the triple oxalate precursor of nickel, cobalt, and manganese was synthesized by liquid-phase co-precipitation method. And then the LiNi1/3Co1/3Mn1/3O2 cathode materials for Li-ion battery were prepared from the precursor and LiOH·H2O by solid-state reaction. The precursor and LiNi1/3Co1/3Mn1/3O2 were characterized by chemical analysis, XRD, EDX, SEM and TG-DTA. The results show that the composition of precursor is Ni1/3Co1/3Mn1/3C2O4·2H2O. The product LiNi1/3Co1/3Mn1/3O2, in which nickel, cobalt and manganese are uniformly distributed, is well crystallized with a-NaFeO2 layered structure. Sintering temperature has a remarkable influence on the electrochemical performance of obtained samples. LiNi1/3Co1/3Mn1/3O2 synthesized at 900 ℃ has the best electrochemical properties. At 0.1C rate, its first specific discharge capacity is 159.7 mA·h/g in the voltage range of 2.75-4.30 V and 196.9 mA·h/g in the voltage range of 2.75-4.50 V; at 2C rate, its specific discharge capacity is 121.8 mA·h/g and still 119.7 mA·h/g after 40 cycles. The capacity retention ratio is 98.27%.
Using oxalic acid and stoichiometrically mixed solution of NiCl2, CoCl2, and MnCl2 as starting materials, the triple oxalate precursor of nickel, cobalt, and manganese was synthesized by liquid-phase co-precipitation method. And then the LiNi1 / 3Co1 / 3Mn1 / 3O2 cathode materials for Li-ion battery were prepared from the precursor and LiOH · H2O by solid-state reaction. The results and LiNi1 / 3Co1 / 3Mn1 / 3O2 were characterized by chemical analysis, XRD, EDX, SEM and TG-DTA. show that the composition of precursor is Ni1 / 3Co1 / 3Mn1 / 3C2O4 · 2H2O. The product LiNi1 / 3Co1 / 3Mn1 / 3O2, in which nickel, cobalt and manganese are uniformly distributed, is well crystallized with a-NaFeO2 layered structure. has a remarkable influence on the electrochemical performance of the obtained samples. LiNi1 / 3Co1 / 3Mn1 / 3O2 synthesized at 900 ℃ has the best electrochemical properties. At 0.1C rate, its first specific discharge capacity is 159.7 mA · h / g in the voltage range of 2.75-4.30 V a nd 196.9 mA · h / g in the voltage range of 2.75-4.50 V; at 2C rate, its specific discharge capacity is 121.8 mA · h / g and still 119.7 mA · h / g after 40 cycles. The capacity retention ratio is 98.27 %.