Novel electrode structure in a DBD reactor applied to the degradation of phenol in aqueous solution

来源 :Plasma Science and Technology | 被引量 : 0次 | 上传用户:zhouheng19850
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Phenol degradation experimental results are presented in a similar wastewater aqueous solution using a non-thermal plasma reactor in a coaxial dielectric barrier discharge. The novelty of the work is that one of the electrodes of the reactor has the shape of a hollow screw which shows an enhanced efficiency compared with a traditional smooth structure. The experimentation was carried out with gas mixtures of 90% Ar–10% O_2, 80% Ar–20% O_2 and 0% Ar–100% O_2. After one hour of treatment the removal efficiency was 76%, 92%, and 97%, respectively, assessed with a gas chromatographic mass spectrometry technique. For both reactors used, the ozone concentration was measured. The screw electrode required less energy, for all gas mixtures, than the smooth electrode, to maintain the same ozone concentration. On the other hand, it was also observed that in both electrodes the electrical conductivity of the solution changed slightly from~0.0115 S m~(-1) up to ~0.0430 S m~(-1) after one hour of treatment. The advantages of using the hollow screw electrode structure compared with the smooth electrode were:(1) lower typical power consumption,(2) the generation of a uniform plasma throughout the reactor benefiting the phenol degradation,(3) a relatively lower temperature of the aqueous solution during the process, and(4) the plasma generation length is larger. Phenol degradation experimental results are presented in a similar aqueous aqueous solution using a non-thermal plasma reactor in a coaxial dielectric barrier discharge. The novelty of the work is that one of the electrodes of the reactor has the shape of a hollow screw which shows an enhanced efficiency compared with a traditional smooth structure. The experimentation was carried out with gas mixtures of 90% Ar-10% O 2, 80% Ar-20% O 2 and 0% Ar- 100% O 2. The screw electrode required less energy, for all gas mixtures, than the smooth electrode, was 76%, 92%, and 97%, respectively, assessed with a gas chromatographic mass spectrometry technique. On the other hand, it was also observed that in both electrodes the electrical conductivity of the solution changed slightly from ~0.0115 S m -1 up to ~ 0.0430 S m -1 after one hour of treatment. The advantages of using the hollow screw electrode structure compared with the smooth electrode were: (1) lower typical power consumption, (2) the generation of a uniform plasma throughout the reactor benefiting the phenol degradation, (3) a relatively lower temperature of the aqueous solution during the process, and (4) the plasma generation length is larger.
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