Novel Chiral Polyoxometalate:First Arginine Based Anderson-type Complex

来源 :Chemical Research in Chinese Universities | 被引量 : 0次 | 上传用户:zhonghuiling2009
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A novel chiral polyoxometalate(POM),{[Na(Arg)2]NaH}[AlMo6(OH)6O18]·6H2O(1,Arg=L-arginine) has been synthesized by the reaction between Na3[AlMo 6(OH)6O18]·8H2 O and Arg in aqueous solution and was structurally characterized by single-crystal X-ray diffraction,elemental analyses and UV-Vis spectrometry.Compound 1 was an example of Arg based Anderson-type complex.Photocatalytic analysis indicates that compound 1 presents catalytic activity for photodegradation of rhodamine-B(RhB) under UV irradiation. A novel chiral polyoxometalate (POM) has been synthesized by the reaction between Na3 [AlMo6 (OH) 6O18] 6H2O (1, Arg = L-arginine) 6O18] .8H20 and Arg in aqueous solution and was structurally characterized by single-crystal X-ray diffraction, elemental analyzes and UV-Vis spectrometry. Compound 1 was an example of Arg based Anderson-type complex. Photocatalytic analysis that compound 1 presents catalytic activity for photodegradation of rhodamine-B (RhB) under UV irradiation.
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