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The title complex [Fe(CDTA)(H2O)]·[Fe(1,10-phen)3]·10H2O·2OH (CDTA = transcyclohexane-1,2-diamine-N,N,N,N′-tetraacetate) has been prepared and characterized by single-crystal X-ray diffraction analysis. The crystal adopts space group P with a = 12.793(4), b = 14.104(5), c = 17.880(5), V = 2792.2(1)3, Dc = 1.459 g/cm3, C50H66Fe2N8O21, Mr = 1226.81, F(000) = 1284, μ = 0.604 mm-1, Z = 2, R = 0.1055 and wR = 0.2581 for 8675 observed reflections (I > 2σ(I)). X-ray crystallography analysis exhibits that the title compound consists of two crystallographically independent molecules [Fe(CDTA)(H2O)] and [Fe(1,10-phen)3], and they are connected through O-H···O hydrogen bonds and π···π stacking interactions forming a 3D supramolecular structure. Interestingly, there is a cyclic water hexamer with chair conformation in this complex.
The title complex [Fe (CDTA) (H2O)] [Fe (1,10-phen) 3] · 10H2O · 2OH (CDTA = transcyclohexane- 1,2-diamine-N, N, N’-tetraacetate) has been prepared and characterized by single-crystal X-ray diffraction analysis. The crystal space group P with a = 12.793 (4), b = 14.104 (5), c = 17.880 (5) 3, Dc = 1.459 g / cm3, C50H66Fe2N8O21, Mr = 1226.81, F (000) = 1284, μ = 0.604 mm-1, Z = 2, R = 0.1055 and wR = 0.2581 for 8675 observed reflections (I> 2σ X-ray crystallography analysis exhibits that the title compound consists of two crystallographically independent molecules [Fe (CDTA) (H2O)] and [Fe (1,10-phen) 3], and they are connected through OH O hydrogen bonds and π · π stacking interactions forming a 3D supramolecular structure. Interestingly, there is a cyclic water hexamer with chair conformation in this complex.