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A new metal-organic coordination polymer [Cd(5-hip)(phen)]n·nH2O 1 has been hydro-ermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The crystal of the complex crystallizes in monoclinic, space group P2/n with a = 8.8071(17), b =12.386(2), c = 16.981(3) , β = 100.182(2)°, V = 1823.2(6) 3, Mr = 490.73, Dc = 1.788 g/cm3, μ(MoKa) = 1.240 mm-1, F(000) = 976, Z = 4, the final R = 0.0458 and wR = 0.1373 for 2864 observed reflections (I > 2σ(I)). The Cd atoms are coordinated by two N atoms from the phen ligands and four O atoms from 5-hydroxyisophthalate ligands in a highly distorted octahedral geometry.
A new metal-organic coordination polymer [Cd (5-hip) (phen)] n · nH2O 1 has been hydro-ermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction complex crystallizes in monoclinic space group P2 / n with a = 8.8071 (17), b = 12.386 (2), c = 16.981 (3) β, β = 100.182 (2) °, V = 1823.2 Mr = 490.73, Dc = 1.788 g / cm3, μ (MoKa) = 1.240 mm-1, F (000) = 976, Z = 4, the final R = 0.0458 and wR = 0.1373 for 2864 observed reflections (I> 2σ The Cd atoms are coordinated by two N atoms from the phen ligands and four O atoms from 5-hydroxyisophthalate ligands in a highly distorted octahedral geometry.