J.Am.Chem.Soc.,2016,138,12037~12040烯烃的氧化反应,比如瓦克氧化(Warker-oxidation),是构建羰基化合物最直接的方法之一,能够实现大宗化工原料烯烃向高价值的醛、酮类化合物的高效转化.然而,传统的烯烃加氧化过程还存在很多的局限性,比如很难实现反马氏选择性的控制,对于内烯的反应活性较低,需要使用昂贵的贵金属催化剂和化学当量的氧化剂等.武汉大学 J. Am. Chem. Soc., 2016, 138, 12037-12040 Oxidation of olefins, such as Warker-oxidation, is one of the most direct ways to construct carbonyl compounds and enables the conversion of bulk chemical feedstock olefins to high However, there are still many limitations of the conventional olefin oxidation process, such as the difficulty of achieving anti-Markov selectivity control, the low reactivity to the internal olefin, and the expensive use of the olefin Precious metal catalyst and stoichiometric oxidant, etc. Wuhan University