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本文研究了氢硼酸根(B_(12)H_(12)~(2-)、B_(10)H_(10)~(1-)、B_(11)H_(14)~-)和π-芳烃-π-环戊二烯基铁阳离子的反应,合成了36个氢硼酸π-芳烃-π-环戊二烯基铁化合物。通过元素分析和红外光谱测定确定了化合物的组成。部份化合物还作了~1H NMR鉴定。对化合物的性质,包括它们的热行为,进行了较详细的研究。DTA仪测得的结果表明,(1)当阳离子相同时,化合物的热稳定性的顺序为:[ArFeC_5H_5]_2B_(12)H_(12)>[ArFeC_5H_5]_2B_(10)H_(10)>[ArFeC_5H_5]B_(11)H_(14);(2)当氢硼酸根相同时,其热稳定性受芳环上取代基的影响。
In this paper, the effects of hydroborate (B_ (12) H_ (12) ~ (2), B_ (10) H_ (10) ~ and B_ (11) H_ (14) -π-cyclopentadienyl iron cations, 36 π-arene-π-cyclopentadienyl iron compounds were synthesized. The composition of the compound was confirmed by elemental analysis and infrared spectroscopy. Some of the compounds were also ~ 1H NMR identification. The properties of compounds, including their thermal behavior, have been studied in more detail. The results of DTA measurement show that (1) the thermal stability of the compounds is the same when the cation is the same: [ArFeC_5H_5] _2B_ (12) H_ (12)> [ArFeC_5H_5] _2B_ (10) H_ ArFeC_5H_5] B_ (11) H_ (14); (2) When the hydroborate is the same, its thermal stability is affected by the substituents on the aromatic ring.