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合成了过渡金属元素Cu与1,10-邻菲啉的配合物并进行了元素分析、红外光谱等表征,测定了配合物的晶体结构。配合物组成为[Cu(phen)3](ClO4)2,属于单斜晶系,P2(1)/n空间群。配合物中金属离子Cu2+处于N6的配位环境,配位构型为六配位的拉长八面体。
The complex of transition metal Cu with 1,10-phenanthroline was synthesized and characterized by elemental analysis and infrared spectroscopy. The crystal structure of the complex was determined. The complex is composed of [Cu (phen) 3] (ClO4) 2 and belongs to the monoclinic space group P2 (1) / n. The metal ions Cu2 + in the complex are in the coordination environment of N6, and the coordination configuration is the elongated octahedron with six coordination.