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研究了Na2CO3/HPAM复合驱介质中溶解氧,以及由碳钢腐蚀产生的Fe2+和Fe3+等对部分水解聚丙烯酰胺(HPAM)降解及粘度变化的影响,并讨论了其作用机制,发现在无氧气氛下腐蚀所产生的Fe2+对HPAM的粘度变化影响不大,而在曝氧环境中,由于Fe2+自动氧化成Fe3+产生了·OH自由基,使HPAM主链断裂而降解,粘度下降很大,降解后的HPAM分子链由于Fe3+的交联作用而沉降.
The effect of dissolved oxygen in Na2CO3 / HPAM composite driving media and the degradation of partially hydrolyzed polyacrylamide (HPAM) and viscosity on the viscosity of Fe2 + and Fe3 + produced by carbon steel corrosion was studied. The mechanism of action was discussed. Under the atmosphere of oxygen, the Fe2 + produced by the corrosion had little effect on the viscosity change of HPAM. However, in the environment of oxygen exposure, the oxidation of Fe2 + to Fe3 + resulted in the formation of · OH radicals, which led to the degradation of the main chain of HPAM, After the HPAM molecular chain due to the crosslinking of Fe3 + and settlement.