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The title complex [Cd2(NO3)2(OCH3)2(TPOM)2]·8H2O (TPOM=tetrakis(4-pyri- dyloxymethylene) methane) has been synthesized and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. It crystallizes in the orthorhombic crystal system Ccca with a=17.125(2), b=40.751(3), c=24.938(2) , β = 90.00o, V= 7403(3) ·3, C26H27N5O8Cd, Mr = 649.93, Z=16, F(000) = 5280, Dc = 0.992 mg/m3, μ(MoKα) =0.538 mm-1, S=1.080, the final R = 0.0533 and wR=0.1449 for 6627 observed reflections (I>2σ(I)). The crystal structure shows that each Cd atom is coordinated to four pyridyl nitrogen atoms from four TPOM ligands and each tetrahedral TPOM ligand links up four Cd atoms into a 2-fold interpenetrating 3D framework. The TG analysis shows that the framework of the title complex is stable up to 300 ℃.
The title complex [Cd2 (NO3) 2 (OCH3) 2 (TPOM) 2] 8H2O (TPOM = tetrakis (4-pyri- dyloxymethylene) methane) has been synthesized and characterized by IR spectroscopy, elemental analysis and single- ray diffraction. It crystallizes in the orthorhombic crystal system Ccca with a = 17.125 (2), b = 40.751 (3), c = 24.938 (2), β = 90.00o, V = 7403 (3) .3, C26H27N5O8Cd, Mr = 649.93, Z = 16, F (000) = 5280, Dc = 0.992 mg / m3, MoKα = 0.538 mm-1, S = 1.080, the final R = 0.0533 and wR = 0.1449 for 6627 observed reflections > 2σ (I)). The crystal structure shows that each Cd atom is coordinated to four pyridyl nitrogen atoms from four TPOM ligands and each tetrahedral TPOM ligand links up four carbon atoms into a 2-fold interpenetrating 3D framework. The TG analysis shows that that the framework of the title complex is stable up to 300 ° C.