We find that five sources listed in the new carbon star catalog are not really carbon-rich objects but oxygen-rich stars, because they all have the prominent 10μm silicate features in absorption and the 1612 MHz OH maser emission or/and the SiO molecular features. These objects were considered as carbon stars in the catalog based only on their locations in the infrared two-color diagram. Therefore to use the infrared two-color diagram to distinguish carbon-rich stars from oxygenrich stars must be done with caution, because, in general, it has only a statistical meaning.