Energy Spectra,g Factors and Their Pressure-Induced and/or Thermal Shifts of SrTiO3:Cr3+ and SrTiO3:

来源 :理论物理通讯 | 被引量 : 0次 | 上传用户:xamalong
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
By using the wavefunctions obtained from diagonalizing the complete ds energy matrix at normal and various pressures,the g factor of the ground state of SrTiO3 :Cr3+ and its pressure-induced shift have been microscopically calculated.Only by taking the local strains around Cr3+ in SrTiO3:Cr3+ (which are about twice the bulk ones) and corresponding P-χ dependence,can we obtain a good agreement between the calculated result of pressure-induced shift of ground-state g factor and the experimental one.The physical origins of this pressure-induced shift have been explained.It is found that the change of Dq-1 with pressure makes main contribution to the pressure-induced shift of ground-state g factor of SrTiO3 :Cr3+.By using the wavefunctions obtained from diagonalizing the complete d3 energy matrix at normal pressure,the relevant matrix elements and accordingly strain-induced splittings of t32 2E and t23 4A2 of SrTiO3:Cr3+ have been calculated.The important results of Yc,Zc,Pc and Qc have also been evaluated.It is the admixtures of basic wavefunctions resulted from the spin-orbit interaction and/or Coulomb interaction and/or Kramers degeneracy that make the strain-induced splittings of the levels nonzero.It is found that there are nonvanishing matrix elements of operators T2,T2rl and T2 between wavefunctions with positive Ms and those with negative M],which have important effects on the strain-induced splittings of the levels.
其他文献
A novel photo-induced initiating system, 2,2-dimethoxy-2-phenylacetophenone (DMPA)/ferric tri(N,N-diethyldithiocarbamate) [Fe(DC)3], was developed and used for
本文试图在反应系统中合成锌配合物晶体,根据结构分析,本标题化合物的晶体则为一种超结构形式.
Two new applications of homogeneous balance (HB) method are presented.It is shown that HB methodcan be extended to search for the Backlund transformations and s
A quadratic scalar and vector coupling model proposed recently has been applied to finite nuclei.The calculated results are compared with those of the derivativ
A numerical analysis to the scalar form factor in the ππ and KK coupled-channel system is made by solving the coupled-channel dispersive integral equations by
Supported Au catalysts for low-temperature CO oxidation were prepared by solvated metal atom impregnation (SMAI) and conventional impregnation (CI). X-ray photo
The physical nature of the auroral electron acceleration has been an outstanding problem in space physics for decades.Some recent observations from the auroral
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
A substituted glycolide, 3-benzyloxymethyl-1,4-dioxane-2,5-dione, was synthesized. It is a suitable precursor for the preparation of a new hydrophilic biodegrad
A better understanding of a recently raised argument on whether there occurs a structure change during yielding has been acquired by using molecular simulation.