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In this paper, a novel polymeric complex [MnNa(Salicylate)_2(CH_3OH)(H_2O)]_n·0.5nH_2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is crystallized in triclinic system, space group P1 with a=0.763 82(15) nm, b= 1.037 1(2) nm, c=1.290 9(3) nm, α= 103.59(3)°, β=104.65(3)°, γ=109.50(3)°, V=0.873 6(3) nm 3, Z=2, D_c=1.556 Mg/m 3, M_r=409.20, μ=0.823 mm -1, F(000)=418, R=0.0614, wR= 0.147 6. The activity in catalyzing the superoxygen anionic free radical dismutation was determinated.
In this paper, a novel polymeric complex [MnNa (Salicylate) _2 (CH_3OH) (H_2O)] _ n · 0.5nH_2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is crystallized in triclinic system = space group P1 with a = 0.763 82 (15) nm, b = 1.037 1 (2) nm, c = 1.290 9 (3) nm, α = 103.59 = 109.50 (3) ° V = 0.873 6 (3) nm 3 Z = 2 D_c = 1.556 Mg / m 3 M_r = 409.20 μ = 0.823 mm -1 F (000) = 418 R = 0.0614 , wR = 0.147 6. The activity in catalyzing the superoxygen anionic free radical dismutation was determinated.