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在七十年代前~(13)C NMR主要是作为有机化学家的工具用来测定有机化合物的分子结构,很少有人注意无机/有机金属络合物。~(13)C NMR逐渐引起无机化学家的兴趣仅是近年来的事情。本文着重讨论~(13)C NMR在有机金属口键络合物中的应用。
Before the seventies ~ (13) C NMR was used as a tool for organic chemists to determine the molecular structure of organic compounds, with little attention being given to inorganic / organometallic complexes. ~ (13) C NMR has gradually attracted the interest of inorganic chemists in recent years. This article focuses on the application of ~ (13) C NMR in organometallic complex.