【摘 要】
：
The title complex [Mn(μ_(1,5)-dca)_2(POM)_2] (C_(16)H_(12)MnN_(10)O_6, M_r = 495.30) has been prepared and structurally characterized. It crystallizes in tricl
【机 构】
：
Department of Chemistry
论文部分内容阅读
The title complex [Mn(μ_(1,5)-dca)_2(POM)_2] (C_(16)H_(12)MnN_(10)O_6, M_r = 495.30) has been prepared and structurally characterized. It crystallizes in triclinic, space group Pi with a = 7.4685(9), b = 7.5406(9), c = 9.8646(12) (A), α = 83.202(2), β = 69.1200(10), γ = 79.4130(10)°, V= 509.38(11) (A)3, Z= 1, D_c= 1.602 g/cm~3, F(000) = 249, μ(MoKa) = 0.704 mm~(-1), the final R = 0.0701 and wR = 0.2071 for 1615 observed reflections with I > 2σ(I). Each Mn(II) exhibits a slightly distorted octahedral environment and connects with each other to form a one-dimensional complex by double bridging μ_(1,5)-N≡C-N-G≡N ligands. The magnetic susceptibility of the title complex has been measured, and it displays weak antiferromagnetic interactions.
其他文献
The new title compound 4-dibenzaldehydeamino-4H-1,2,4-triazole diacetate (C_(16)H_(18)N_8O_4, M_r = 386.38) has been prepared and its crystal structure was dete
A novel cobalt(II) coordination polymer, [Co(BTEC)_(1/2)]_n 1, has been synthesized with Co(NO_3)_2·6H_2O and 1,2,4,5-benzenetetracarboxylic acid (H4BTEC) by t
Aristolochic acid (AA) is a known nephrotoxin and potential carcinogen, which can form covalent DNA adducts after metabolic activation in vivo and in vitro. A s
Oxone (3.5 mol%) was found to be an effective catalyst for the condensation reactions of indoles with aldehydes to afford bis-indolylmethanes in good to excelle
A new macrocycle based on diethoxycarbonyl glycoluril 3, C_(26)H_(30)N_6O_(10), has been synthesized and characterized by single-crystal X-ray diffraction. It c
A rapid and simple preeoncentration step applying packed-fiber solid-phase extraction columns has been investigated to vitamin B_(12). The extraction performanc
Doping amine functional groups into SiO_2/TiO_2 films for enhancing the decomposition of formaldehyde has been investigated using the modified sol-gel method to
The Eu~(3+):BaMoO_4 nanostructures were synthesized by a simple hydrothermal method, and characterized by XRD, transmission electron microscopy, high-resolution
Boric acid (BO_3H_3) is an inexpensive, efficient and mild catalyst for the synthesis of 1,1-diacetate (acylal) from the various aromatic and heteroaryl aldehyd
A novel carbonaceous adsorbent for heavy metal removal was prepared from raw coal by one-step simple sulfur impregnation using K_2S. Raw coal was mixed with K_2