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共振论是鲍林将量子力学引入化学所做的最根本贡献,它在科学和非科学界遭遇持久争论。共振论批判的意识形态特点多受到关注,其在科学领域的影响被忽略。本文分析了鲍林引入共振论并介绍给化学家的方式,探析了共振论在科学界引起争论、以及争论之后成为化学领域基础概念的原因,并考察了中国科学家在科学层面应对共振论争论的模式。研究发现:共振论以非数学方式沟通量子力学与化学,用化学家熟悉的概念和方式去描述新概念,以及有机化学的学科特征中的结构和分子的图形符号表征,为量子化学这门亚学科的自主性提供了张力;通过对结构和价键进行分离的方法解决本体论问题,保留价键理论的化学本质,是争论后共振论被广泛接受的原因。
Resonance theory is Pauling’s most fundamental contribution to the introduction of quantum mechanics into chemistry, and it has encountered lasting controversy among the scientific and non-scientific communities. The ideological features of the critique of resonance theory have drawn much attention and their influence in the field of science has been neglected. This article analyzes Pauling ’s introduction of resonance theory and its introduction to chemists. It explores why resonance theory has caused controversy in the scientific community and has become the basic concept in the field of chemistry after controversy. It also examines how Chinese scientists deal with the argument of resonance theory at the scientific level mode. The study found that resonance theory communicates quantum mechanics and chemistry non-mathematically, uses the familiar concepts and methods of chemists to describe new concepts, and the structural and molecular symbolic representations of the discipline features of organic chemistry for quantum chemistry Discipline autonomy provided tension; the problem of ontology was solved by separating the structure and the valence bond, and the chemical nature of the valence bond theory was retained, which was the reason why the post-debate resonance theory was widely accepted.