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应用低温(77K)ESR测定了一些有机磷化合物在低温(77K)γ辐照所产生的自由基,并以质谱及原子部分电荷计算结果,讨论了磷酸酯及膦酸酯的键结构与辐射稳定性的关系。
The free radicals produced by some organophosphorus compounds at low temperature (77K) γ irradiation were measured by low temperature (77K) ESR, and the bond structure and radiation stability of phosphate ester and phosphonate ester were discussed based on mass spectra and atomic charge calculations Sexual relations.