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The measurement and control of high temperature play very important roles in national defense, mili-tary, scientific experiments, industrial and agricultural production. Photoelectric pyrometer is one of the important radiation thermometers for non-contact temperature measurement. It has an important application in the field of high temperature measurement, and its performance directly affects the ac-curacy of temperature measurement. By improving the design of the detection optical system of the photoelectric pyrometer, the imaging performance of the photoelectric pyrometer can be improved effectively, and the temperature measurement accuracy can be improved. In this paper, the temperature measurement principle of photoelectric pyrometer, the working principle of the detection optical system and the composition of the system are introduced. The optical components that affect the imaging of the optical system of the photoelectric pyrometer are analyzed. The optical pyrometer detection optical system is simulated by ZEMAX software, based on the analysis results, the Modulation Transfer Function (MTF) and the spot Diagram are used as the main evaluation criteria to optimize the design of the objective lens of the photoelectric pyrometer detection optical system. The imaging performance of the photoelectric pyrometer detection optical system and the accuracy of temperature measurement of the photoelectric pyrometer are improved by optimization design of the detection optical system.