一种简易、价廉的新方法,可以有效地将任何芳基膦转变成相应的环己基膦(CHP)。该工艺可以一步合成许多新的 CHP 类产品,其中不少已经由其发明者 Purdue 大学的 Ian Rothwell 和 Joyce 博士制成。CHP 类在许多催化过程中例如氢化、硅氢化、硼氢化、和碳鎓离子转化中是重要的配位体。价廉的新CHP 类较相应的芳基化合物在许多生产药物、生物化学品和农业化学品的合成工艺中,允许更大的立体 A simple, inexpensive new method that efficiently converts any arylphosphine to the corresponding cyclohexylphosphine (CHP). The process can synthesize many new CHP products in a single step, many of which have been made by Ian Rothwell and Joyce, PhD, Purdue University. CHP classes are important ligands in many catalysis processes such as hydrogenation, hydrosilation, hydroboration, and carbonium ion conversion. The cheaper new CHP than the corresponding aryl compounds in many synthetic processes for the production of pharmaceuticals, biologics and agrochemicals, allows for a larger stereo