论文部分内容阅读
羟酸酯用硼氢化钙还原为醇或醛NarasimhanS等[SynCommun,1995;25:1689]CaCl2与NaBH4在THF中作用生成的硼氢化钙在烯烃(如1,5-环辛二烯)催化下,可将脂肪族酯和芳香族酯高收率地还原为醇;芳香族酯还原的中间体──...
Hydroxylates with calcium borohydride to alcohols or aldehydes Narasimhan S et al [SynCommun, 1995; 25: 1689] Calcium borohydride formed by the action of CaCl 2 and NaBH 4 in THF Catalyzed by olefins such as 1,5-cyclooctadiene , Aliphatic esters and aromatic esters can be reduced to high yield alcohol; aromatic ester reduction intermediates ─ ─ ...