本文根据文献[4]提出的配位场理论方法,采用SLГ_SГtτ方案,对晶体K_2PtCl_6中Re~(+4)(5d~3)和Os~(+4)(5d~4)离子能谱进行全分析,考虑了全部d~3和d~4组态的静电作用能,正八面体场势能和旋轨偶合作用能,计算了能级随参数变化曲线,能谱理论计算结果与文献[9—10]强场方案计算结果一致,但改正了前人对实验能谱指认不正确之处。 Based on the ligand field theory proposed in [4], the energy spectra of Re ~ (+4) (5d ~ 3) and Os ~ (+4) (5d ~ 4) ions in K_2PtCl_6 crystal were completely solved by SLГ_SГtτ The electrostatic potential energy, the potential energy of the octahedron and the coupling energy of the spinodal coupling are taken into account for all d ~ 3 and d ~ 4 configurations. The energy level curves with parameters are calculated. ] Strong field scheme has the same calculation results, but corrected the previous incorrect recognition of the experimental spectrum.