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以3-对溴苯基-4-对甲苯基-5-(2-吡啶基)-1,2,4-三氮唑(L)作为配体,合成了1个铜配合物trans-[CuL2(ClO4)2],对其进行了红外、电喷雾质谱、热重分析和单晶结构表征,该配合物属于三斜晶系,空间群P1,a=0.829 29(15)nm,b=0.854 48(16)nm,c=1.502 7(3)nm,α=83.517(2)°,β=89.200(2)°,γ=73.064(2)°,V=1.011 9(3)nm3,Z=1,R1=0.041 2。单晶结构表明,铜离子处于1个扭曲的八面体配位环境中,2个高氯酸根离子呈反式配位,每个配体L通过三氮唑上的1个氮原子和吡啶氮原子参与配位。热重分析表明该配合物在310℃开始发生分解。
A copper complex, trans- [CuL2], was synthesized using 3-p-bromophenyl-4-p-tolyl-5- (2-pyridyl) -1,2,4-triazole (L) (ClO4) 2] was synthesized and characterized by IR, ESI-MS, TG and single crystal structure. The complex belongs to the triclinic system with a space group P1, a = 0.829 29 (15) nm and b = 0.854 Α = 83.517 (2) °, β = 89.200 (2) °, γ = 73.064 (2) °, V = 1.011 9 (3) nm3 and Z = 1, R1 = 0.041 2. Single crystal structure shows that copper ions in a twisted octahedral coordination environment, two perchlorate ion trans-coordination, each ligand L through a triazole nitrogen and pyridine nitrogen atom Participate in coordination. Thermogravimetric analysis showed that the complex began to decompose at 310 ℃.