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(±)4,10-二氧杂三环[5,2,1,02,6]-癸-8-烯-3-醇在ZnBr2催化下与格氏试剂反应得S-二醇4a,而与街进制AT(OPr-i)3单独作用则得R-H醇4b。探讨了反应机理,并提出了合成不同构型乳醇的新方法。
(±) 4,10-dioxa-tricyclo [5,2,1,02,6] -dec-8-en-3-ol is reacted with Grignard reagent under ZnBr2 catalysis to obtain S-diol 4a, while R-H alcohol 4b is obtained by acting alone with the AT (OPr-i) 3. The reaction mechanism was discussed, and a new method of synthesizing different configurations of lactols was proposed.