【摘 要】
：
A novel Pd(II) Benzo-15-crown-5 complex [Na(B15CS)]_2[Pd(SCN)_4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
A novel Pd(II) Benzo-15-crown-5 complex [Na(B15CS)]_2[Pd(SCN)_4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P2_1,/n with cell dimensions, a = l.0164(6), b = l.3743(3), c = l.4987(7) nm, β = 95.248(6) °, V = 2.0847 “nm_3, Z = 2, F(000) = 944, R = 0.053, Rw = 0.072. The compound consists of two [Na(B15CS)]+ complex canons and a [Pd(SCN)4_]~(2-) complex anion. Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of [Pd(SCN)_4]~(2-) to form stable neutral complex.
A novel Pd (II) Benzo-15-crown-5 complex [Na (B15CS)] _2 [Pd (SCN) _4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P2_1, / n with cell dimensions, a = l.0164 (6), b = l.3743 (3), c = l.4987 (7) nm, β = 95.248 (6) °, V = 2.0847 ” The complex consists of two [Na (B15CS)] + complex canons and a [Pd (SCN) 4_] ~ (2-) complex anion. Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of [Pd (SCN) _4] ~ (2-) to form stable neutral complex.
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