石墨电弧中C5环的原位捕获与形成

来源 :厦门大学学报（自然科学版） | 被引量 : 0次 | 上传用户：ynjdxyzzz

【摘要】

：

五元环是富勒烯的重要构筑基元,是形成凸多面体碳笼的关键因素,研究C5环的形成对理解富勒烯自下而上的生长机理有着重要的意义.该文通过在石墨电弧放电体系中引入氯源,原位捕

【作者】

：

石祥美田寒蕊谢芳芳姚阳榕张美林谢素原黄荣彬郑兰荪

【机构】

：

厦门大学化学化工学院,固体表面物理化学国家重点实验室,福建厦门 361005

【出处】

：

厦门大学学报（自然科学版）

【发表日期】

：

2020年1期

【关键词】

：

环戊二烯富勒烯电弧放电环加成反应

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

五元环是富勒烯的重要构筑基元,是形成凸多面体碳笼的关键因素,研究C5环的形成对理解富勒烯自下而上的生长机理有着重要的意义.该文通过在石墨电弧放电体系中引入氯源,原位捕获到了C5与C60的[4+2]环加成衍生物C60(C5 Cl6).对该分子进行质谱和紫外-可见吸收光谱的表征,并利用X-射线单晶衍射明确了C60(C5 Cl6)的分子结构.此外,还通过一系列C60衍生物的质谱表征,对C5环和C60(C5 Cl6)结构的演进路线进行了分析.

其他文献

小儿阑尾炎术后肠套叠1例

胜利油田中心医院收治1例急性阑尾炎患儿,术后出现肠套叠,反复空气灌肠复位失败后行手术治疗,并进行术后随访,为以后的临床治疗提供指导.

期刊

急性阑尾炎肠套叠

Approximate Quadratic Functional Inequality in β-Homogeneous Normed Spaces

Using the direct method,we investigate the generalized Hyers-Ulam stability of the following quadratic functional inequality]] f(x-y) + f(y-z) + f(x-z)-3f(x)-3f

期刊

β-homogeneous spacegeneralized Hyers-Ulam stabilityquadratic functional inequa

Directional Preimage Entropy for Zk+-Actions

In this paper,a new type of entropy,directional preimage entropy including topological and measure theoretic versions for Zk+-actions,is introduced.Some of thei

期刊

Zk+-actionsdirectional preimage entropyinfinite graph

Explicit Iterative Sequences of Positive Solutions for a Class of Fractional Differential Equations

By applying the monotone iterative method,this study develops two explicit monotone iterative sequences for approximating the minimal and maximal positive solut

期刊

monotone iterative methoditerative sequencesfractional differential equations

Indefinite Least Squares Problem with Quadratic Constraint and Its Condition Numbers

In this paper,we consider the indefinite least squares problem with quadratic constraint and its condition numbers.The conditions under which the problem has th

期刊

indefinite least squares problemquadratic constraintnormwise condition number

Verified Computation of Eigenpairs in the Generalized Eigenvalue Problem for Nonsquare Matrix Pencil

Consider an optimization problem arising from the generalized eigenvalue problem Ax =λBx,where A,B ∈ Cm×n and m ＞ n.Ito et al.showed that the optimization pro

期刊

generalized eigenvalue problemnonsquare pencilinvariant subspaceverified nume

On L-Covering Mappings and 1-L-Covering Mappings

In this paper,we introduce the concepts of L-covering mappings and 1-L-covering mappings,discuss the difference between sequence-covering and L-covering mapping

期刊

ideal convergenceL-covering mappings1-L-covering mappingscompact mappings

The Number of Failed Components in a Conditional Coherent Operating System

Coherent systems are very important in reliability,survival analysis and other life sciences.In this paper,we consider the number of failed components in an (n-

期刊

coherent systemstochastic orderIFRmeansignature

Curve Reconstruction Algorithm Based on Discrete Data Points and Normal Vectors

This paper presents a curve reconstruction algorithm based on discrete data points and normal vectors using B-splines.The proposed algorithm has been improved i

期刊

curve reconstructioncurve fittingnormal vectorB-splinedominant point

(n,k)-星图的嵌入连通度

星图S n,k的h-嵌入连通度ζh(S n,k)(h-嵌入边连通度ηh(S n,k))被定义为顶点子集(边子集)的最小基数,如果存在,将其删除后Sn,k不连通而且连通分支的每个顶点都位于h-维的子

期刊

互联网络连通度(nk)-星图h-嵌入(边)连通度

石墨电弧中C5环的原位捕获与形成

其他学术论文