高聚物非晶态的玻璃化转变的理论研究,提出了几种机理,而非晶态的结构研究,也提出了各种模型。本文试将玻璃化转变看成是非晶态的结构转变,提出一种玻璃化转变的微观解释——局部有序化假设,并用其说明非晶态的各种状态可用不同的模型来表示,最后给出了有待实验验证的几点推论。 Several studies have been made on the theory of non-crystalline glass transition of polymers, and several kinds of mechanisms have been proposed. However, various models have also been proposed for the study of amorphous structure. This paper attempts to consider the glass transition as a non-crystalline structural change, and proposes a microscopic explanation of the glass transition - the assumption of local ordering, and states that various states of the amorphous state can be represented by different models, and finally Some experiments to be verified are given.