X射线单晶结构分析结果表明,标题化合物晶体—ZnVAL C_(28)H_(30)N_4O_4SZn属正交晶系,空间群P2_12_12_1,a=0.9259(2),b=1.4409(4),c=2.1046(8)nm,Z=4,最终因子R_w=0.080.利用热重分析对配合物第一步热分解过程进行了非等温动力学研究,探讨了反应的可能机理,得到了其相应的动力学参数,非等温动力学方程为:da/dt=A·e~(-E/RT)3/2(1-α)~(4/3)[1/(1-α)~(1/3)-1]~(-1) The results of X-ray single crystal structure analysis show that the crystal of the title compound -ZnVAL C_ (28) H_ (30) N_4O_4SZn belongs to the orthorhombic system with space group P2_12_12_1, a = 0.9259 (2), b = 1.4409 (8) nm, Z = 4 and the final factor R_w = 0.080. The thermogravimetric analysis was used to study the non-isothermal kinetics of the first step pyrolysis of the complex. The possible mechanism of the reaction was discussed. The corresponding kinetics The parameters and non-isothermal kinetic equations are: da / dt = A · e ~ (-E / RT) 3/2 (1-α) ~ (4/3) [1 / (1-α) ) -1] ~ (-1)