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本文作者之一曾在鲍林金属电子论的基础上,应用余瑞璜20年来所建立起来的固体与分子经验电子理论,建立了三价锕系元素的单键半径R(1)的普遍公式,及其杂阶表,为了证实这一公式的适用性,本文对三阶锕系元素的氧化物进行了价电子结构分析,给出了键电子结构,其键距差均在允许误差之内,证明了此公式对三价锕系的氧化物是适用的。同时,为三价锕系的氧化物的性能分析提供了价电子结构方面的基本数据。
On the basis of Pauling’s theory of metallic electronics, one of the authors of this article established the universal formula for the single-bond radius R (1) of trivalent actinides using the solid and molecule empirical electronic theory developed by Yu Ruihuang over the past 20 years and In order to verify the applicability of this formula, the electronic structure of the third-order actinides was analyzed. The bond-electron structure was given, and the bond distance difference was within the allowable error. This formula is suitable for trivalent actinide oxides. At the same time, the basic data of the valence electron structure for the performance analysis of the trivalent actinide oxides are provided.