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采用溶剂热法合成[Cu2L2](L=2,4-dichloro-6-{[(2-hydroxyphenyl)amino]methyl}phenol),并通过红外光谱、元素分析、X-射线单晶衍射进行表征。该化合物属于单斜晶系,P21/n空间群,晶胞参数:a=12.932 2(10),b=5.083 2(4),c=14.760 9(11),β=96.069(7)°,V=1 241.7(11)3,Z=4,Dx=1.924 mg.m-3,μ=2.19 mm-1,F(000)=716,R[F2>2σ(F2)]=0.175,wR(F2)=0.252。结构分析表明,配合物为具有手性对称的平面结构。
[Cu2L2] (L = 2,4-dichloro-6 - {[(2-hydroxyphenyl) amino] methyl} phenol was synthesized by solvothermal method and characterized by IR, elemental analysis and X-ray single crystal diffraction. The compound belongs to the monoclinic space group P21 / n with unit cell parameters of a = 12.932 2 (10) , b = 5.083 2 (4) , c = 14.760 9 ) 2, V = 1 241.7 (11) 3, Z = 4, Dx = 1.924 mg.m -3, μ = 2.19 mm -1, F 000 = 716, 0.175, wR (F2) = 0.252. Structural analysis shows that the complex has a planar structure with chiral symmetry.