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本文通过对电解过程的深入研究,用数学的方法给出了法拉第的两个电解定律的理论性证明,从理论上给出了法拉第第二电解定律中普适恒量的本质解释并且证明了它就是一个法拉第的倒数,本文还研究了阿弗加德罗常数与一个法拉第的电量及一个电子的电量之间的关系,给出了阿弗加德罗常数的一个更为精确的结果,即L=6.02204X10 ̄(23),由于纯粹由实验归纳而得到的两个法拉第电解定律是电化学理论的基础,因此对这两个电解定律的理论证明就显得特别地有理论价值。
In this paper, through deep research on the electrolysis process, we theoretically prove Faraday’s two laws of electrolysis mathematically and theoretically give the essential explanation of the universal law of Faraday’s second law of electrolysis and prove that it is A reciprocal of Faraday, this paper also studies the relationship between the Avogadroic constant and the power of a Faraday and an electron’s power, giving a more accurate result of the Avogadro’s constant, that is, L = 6.02204X10 ~ (23). Since the two Faraday’s laws of electrolysis obtained purely by experimental induction are the basis of electrochemical theory, the theoretical proof of these two laws of electrolysis is of particular theoretical value.